Solutions of Gallium Trichloride in Ethers: A 71 Ga NMR Study and the X-Ray Structure of GaCl3 • Monoglyme
نویسندگان
چکیده
Solutions o f G aC l3 in various ethers have been studied by 7lG a N M R spectroscopy. <S7lG a data indicate tha t the predom inant species in d iethylether and tetrahydrofuran solutions are G aC l3 0 (C 2H 5) 2 and G aC l3 -2 0 C 4 H g, respectively. However, in monoglyme solution disso ciation occurs and the product crystallizing from the solution is [c7's-G aCl2(m onoglym e)2]G aC l4 as dem onstrated by an X -ray structure determ ination o f the solvate G aC l3 • monoglyme.
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